Alfonso GRASSI | SUSTAINABLE CATALYSIS

cod. 0522300045

SUSTAINABLE CATALYSIS

	0522300045
	DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI"
	EQF7
	CHEMISTRY
	2017/2018

CURRICULUM SUSTAINABLE CHEMISTRY

	OBBLIGATORIO
	YEAR OF COURSE 1
	YEAR OF DIDACTIC SYSTEM 2016
	SECONDO SEMESTRE

TEACHING UNITS

	SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
	CHIM/03	12	96	LESSONS	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS

PROFESSORS

	CLAUDIO PELLECCHIA T Curriculum
	CARMINE CAPACCHIONE Curriculum
	ALFONSO GRASSI Curriculum

	Objectives
	THE PURPOSE OF THE COURSE IS TO INTRODUCE THE STUDENT TO THE SUSTAINABILITY CRITERIA OF CATALYTIC PROCESSES IN ACCORDANCE WITH THE PRINCIPLES OF GREEN CHEMISTRY. THE STUDENT WILL LEARN MECHANISMS OF REACTIONS AND REACTION CONDITIONS (SOLVENT, TEMPERATURE, REAGENTS, EFFICIENCY CATALYTIC) THAT MAKE SUSTAINABLE REACTIONS AS FUNDAMENTAL REDUCTION, OXIDATION, TRAINING TIE C-C. THE MAIN CLASSES OF METALLIC CATALIZERS (HOMOGENEES, SUPPORTED, METALLIC NANOPARTICLES) HAVE EXAMINED HIGH EFFICIENCY AND ENVIRONMENTAL COMPATIBILITY OF PROCESSES. AT THE END OF THE COURSE, THE STUDENT WILL HAVE TO BE ABLE TO IDENTIFY AND EVALUATE THE OPTIMUM EXPERIMENTAL CONDITIONS FOR THE EFFICIENT AND SUSTAINABLE REALIZATION OF A CATALYTIC PROCESS AND TO EVALUATE THE ENVIRONMENTAL IMPACT..

THE PURPOSE OF THE COURSE IS TO INTRODUCE THE STUDENT TO THE SUSTAINABILITY CRITERIA OF CATALYTIC PROCESSES IN ACCORDANCE WITH THE PRINCIPLES OF GREEN CHEMISTRY. THE STUDENT WILL LEARN MECHANISMS OF REACTIONS AND REACTION CONDITIONS (SOLVENT, TEMPERATURE, REAGENTS, EFFICIENCY CATALYTIC) THAT MAKE SUSTAINABLE REACTIONS AS FUNDAMENTAL REDUCTION, OXIDATION, TRAINING TIE C-C. THE MAIN CLASSES OF METALLIC CATALIZERS (HOMOGENEES, SUPPORTED, METALLIC NANOPARTICLES) HAVE EXAMINED HIGH EFFICIENCY AND ENVIRONMENTAL COMPATIBILITY OF PROCESSES. AT THE END OF THE COURSE, THE STUDENT WILL HAVE TO BE ABLE TO IDENTIFY AND EVALUATE THE OPTIMUM EXPERIMENTAL CONDITIONS FOR THE EFFICIENT AND SUSTAINABLE REALIZATION OF A CATALYTIC PROCESS AND TO EVALUATE THE ENVIRONMENTAL IMPACT..

	Prerequisites
	KNOWLEDGE OF INORGANIC CHEMISTRY AND COORDINATION CHEMISTRY

	Contents
	PRINCIPLES OF GREEN CHEMISTRY. ATOM ECONOMY. E-FACTOR. CARBON FOOTPRINT. LIFE CYCLE ASSESSMENT: ASSESSING THE SUSTAINABILITY OF A CATALYTIC PROCESS. CATALYSIS IN SUSTAINABLE SOLVENTS: CHOICE OF SOLVENT, WATER, BIPHASIC AQUEOUS SYSTEMS, MULTI-PHASE SYSTEMS. CARBON DIOXIDE AS SUPERCRITICAL FLUID. IONIC LIQUIDS.MICROWAVE IN CATALYSIS. OPERATING PRINCIPLE: MICROWAVE HEATING. THE ROLE OF WATER AS A SOLVENT. HOMOGENOUS CATALYSIS ASSISTED BY MICROWAVES. PHOTOCATALYSTS. TITANIUM DIOXIDE. ACTIVATION OF C-H BONDS. ACTIVATION OF C-N AND C-CL BONDS. C-C BONDS BREAK. PHOTODECOMPOSITION OF SULFUR-CONTAINING COMPOUNDS. VALUATION OF CARBON DIOXIDE REDUCTION OF CARBON DIOXIDE: SYNTHESIS OF METHANOL, FORMALDEHYDE AND FORMIC ACID. SYNTHESIS OF CARBONATES AND POLYCARBONATES FROM CO2. CO2 REACTION WITH DOUBLE AND TRIPLE BONDS. OTHER REACTIONS WITH CARBON DIOXIDE. MOLECULES OF INDUSTRIAL INTEREST FROM RENEWABLE SOURCES BIOMASS OF FIRST, SECOND AND THIRD GENERATION. BIODIESEL AND BIOREFINERY; DROP SYNTHESIS OF OLEFINS, LACTIC ACID, GLYCEROL AND ITS DERIVATIVES, 1,3 PROPANDIOL, ITACONIC ACID, HMF AND FURFURAL, LEVULINIC ACID, FATTY ACIDS AND TERPENES. ACIDIC AND BASICS HETEROGENEOUS CATALYSIS. ACID, CLAY AND ZEOLITE SUPPORTS, SULPHONATED POLYMERS, HYDROTALCITES AND BASIC ZEOLITES, BASIC CATALYSTS SUPPORTED ON SILICA. SUPPORTED METAL CATALYSTS. HETEROGENIZATION OF HOMOGENOUS CATALYSTS. METALS SUPPORTED ON INORGANIC AND POLYMERIC MATRICES. METAL NANOPARTICLES IN SUSTAINABLE CATALYSIS. SYNTHESIS AND CATALYTIC APPLICATIONS OF NOBLE METAL NANOPARTICLES. CATALYTIC REDUCTIONS. HYDROGEN FROM RENEWABLE SOURCES. HYDROGEN REDUCTION REACTIONS. HYDROGEN BORROWING. REDUCTION WITH ALTERNATIVE SYSTEMS TO HYDROGEN.BASICS OF CHEMICAL KINETIC. STEREOCHEMISTRY. NUCLEOPHILIC SUBSTITUTIONS ON SQUARE PLANAR, TETRAHEDRAL AND OCTAHEDRAL CENTRES. INSERTION REACTIONS. REDOX REACTIONS. OXIDATIVE INSERTION REACTIONS METAL MULTIPLE BONDS AND CLUSTER COMPOUNDS. BIO-INORGANIC CHEMISTRY: PRESENCE OF INORGANIC COMPOUNDS IN LIVING ORGANISMS. BIOLOGICAL LIGANDS FOR METAL IONS. SELECTED EXAMPLES OF REACTIONS CATALYZED BY METAL COMPLEXES : HYDROGENATION AND RELATED REACTIONS; HYDROFORMYLATION; CARBONYLATION; OXIDATION OF OLEFINS; METATHESIS; POLYMERIZATION AND OLIGOMERIZATION OF OLEFINS AND OTHER HYDROCARBURIC UNSATURATED MONOMERS . STUDY CASES RELATED TO THE LETTERATURE RECENT CATALYTIC OXIDATION. MECHANISTIC CONSIDERATIONS: HOMOLYTIC AND HETEROLYTIC OXIDATION, OXIDATION OF ALKENES TO EPOXIDES, OXIDATIVE CLEAVAGE OF THE DOUBLE BOND, OXIDATION OF AROMATIC COMPOUNDS AND ALKANES, OXIDATION OF ALCOHOLS, OXIDATIONS OF ALDEHYDES AND KETONES, OXIDATION OF AMINES, ASYMMETRIC OXIDATION.

Contents

PRINCIPLES OF GREEN CHEMISTRY. ATOM ECONOMY. E-FACTOR. CARBON FOOTPRINT. LIFE CYCLE ASSESSMENT: ASSESSING THE SUSTAINABILITY OF A CATALYTIC PROCESS. CATALYSIS IN SUSTAINABLE SOLVENTS: CHOICE OF SOLVENT, WATER, BIPHASIC AQUEOUS SYSTEMS, MULTI-PHASE SYSTEMS. CARBON DIOXIDE AS SUPERCRITICAL FLUID. IONIC LIQUIDS.MICROWAVE IN CATALYSIS.
OPERATING PRINCIPLE: MICROWAVE HEATING. THE ROLE OF WATER AS A SOLVENT. HOMOGENOUS CATALYSIS ASSISTED BY MICROWAVES.
PHOTOCATALYSTS. TITANIUM DIOXIDE. ACTIVATION OF C-H BONDS. ACTIVATION OF C-N AND C-CL BONDS. C-C BONDS BREAK. PHOTODECOMPOSITION OF SULFUR-CONTAINING COMPOUNDS. VALUATION OF CARBON DIOXIDE
REDUCTION OF CARBON DIOXIDE: SYNTHESIS OF METHANOL, FORMALDEHYDE AND FORMIC ACID. SYNTHESIS OF CARBONATES AND POLYCARBONATES FROM CO2. CO2 REACTION WITH DOUBLE AND TRIPLE BONDS. OTHER REACTIONS WITH CARBON DIOXIDE.

MOLECULES OF INDUSTRIAL INTEREST FROM RENEWABLE SOURCES
BIOMASS OF FIRST, SECOND AND THIRD GENERATION. BIODIESEL AND BIOREFINERY; DROP SYNTHESIS OF OLEFINS, LACTIC ACID, GLYCEROL AND ITS DERIVATIVES, 1,3 PROPANDIOL, ITACONIC ACID, HMF AND FURFURAL, LEVULINIC ACID, FATTY ACIDS AND TERPENES. ACIDIC AND BASICS HETEROGENEOUS CATALYSIS. ACID, CLAY AND ZEOLITE SUPPORTS, SULPHONATED POLYMERS, HYDROTALCITES AND BASIC ZEOLITES, BASIC CATALYSTS SUPPORTED ON SILICA. SUPPORTED METAL CATALYSTS. HETEROGENIZATION OF HOMOGENOUS CATALYSTS. METALS SUPPORTED ON INORGANIC AND POLYMERIC MATRICES. METAL NANOPARTICLES IN SUSTAINABLE CATALYSIS. SYNTHESIS AND CATALYTIC APPLICATIONS OF NOBLE METAL NANOPARTICLES.

CATALYTIC REDUCTIONS. HYDROGEN FROM RENEWABLE SOURCES. HYDROGEN REDUCTION REACTIONS. HYDROGEN BORROWING. REDUCTION WITH ALTERNATIVE SYSTEMS TO HYDROGEN.BASICS OF CHEMICAL KINETIC. STEREOCHEMISTRY. NUCLEOPHILIC SUBSTITUTIONS ON SQUARE PLANAR, TETRAHEDRAL AND OCTAHEDRAL CENTRES. INSERTION REACTIONS. REDOX REACTIONS. OXIDATIVE INSERTION REACTIONS
METAL MULTIPLE BONDS AND CLUSTER COMPOUNDS.
BIO-INORGANIC CHEMISTRY: PRESENCE OF INORGANIC COMPOUNDS IN LIVING ORGANISMS. BIOLOGICAL LIGANDS FOR METAL IONS.
SELECTED EXAMPLES OF REACTIONS CATALYZED BY METAL COMPLEXES :
HYDROGENATION AND RELATED REACTIONS;
HYDROFORMYLATION;
CARBONYLATION;
OXIDATION OF OLEFINS;
METATHESIS;
POLYMERIZATION AND OLIGOMERIZATION OF OLEFINS AND OTHER HYDROCARBURIC UNSATURATED MONOMERS .
STUDY CASES RELATED TO THE LETTERATURE RECENT
CATALYTIC OXIDATION. MECHANISTIC CONSIDERATIONS: HOMOLYTIC AND HETEROLYTIC OXIDATION, OXIDATION OF ALKENES TO EPOXIDES, OXIDATIVE CLEAVAGE OF THE DOUBLE BOND, OXIDATION OF AROMATIC COMPOUNDS AND ALKANES, OXIDATION OF ALCOHOLS, OXIDATIONS OF ALDEHYDES AND KETONES, OXIDATION OF AMINES, ASYMMETRIC OXIDATION.

	Teaching Methods
	LECTURES

	Verification of learning
	WRITTEN EXAMINATION WITH OPEN QUESTIONS; ORAL EXAM

	Texts
	R.A SHELDON, I. ARENDS, U. HANEFELD “GREEN CHEMISTRY AND CATALYSIS” WILEY-VCH ED. P.T. ANASTS “GREEN CATALYSIS” - WILEY-VCH ED. F.A. COTTON, J. WILKINSON “CHIMICA INORGANICA”-ED. AMBROSIANA C. ELSCHENBROICH, A. SALZER "ORGANOMETALLICS" – ED. VCH. J.F. HARTWIG "ORGANOTRANSITION METAL CHEMISTRY -UNIVERSITY SCIENCE BOOKS UPDATED REVIEWS FURNISHED BY THE TUTORS ON SPECIFIC SUBJECTS PRESENTED DURING THE SEMINARS.

Texts

R.A SHELDON, I. ARENDS, U. HANEFELD “GREEN CHEMISTRY AND CATALYSIS” WILEY-VCH ED.
P.T. ANASTS “GREEN CATALYSIS” - WILEY-VCH ED.
F.A. COTTON, J. WILKINSON “CHIMICA INORGANICA”-ED. AMBROSIANA
C. ELSCHENBROICH, A. SALZER "ORGANOMETALLICS" – ED. VCH.
J.F. HARTWIG "ORGANOTRANSITION METAL CHEMISTRY -UNIVERSITY SCIENCE BOOKS
UPDATED REVIEWS FURNISHED BY THE TUTORS ON SPECIFIC SUBJECTS PRESENTED DURING THE SEMINARS.

	More Information
	LANGUAGE OF INSTRUCTION: ITALIAN ADDITIONAL INFORMATION: FURTHER INFORMATION CAN BE REQUESTED VIA E-MAIL: PLONGO@UNISA.IT

BETA VERSION Data source ESSE3 [Ultima Sincronizzazione: 2019-05-14]

Alfonso GRASSI | SUSTAINABLE CATALYSIS