INORGANIC CHEMISTRY II

Claudio PELLECCHIA INORGANIC CHEMISTRY II

0512400007
DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI"
EQF6
CHEMISTRY
2016/2017

OBBLIGATORIO
YEAR OF COURSE 3
YEAR OF DIDACTIC SYSTEM 2010
PRIMO SEMESTRE
CFUHOURSACTIVITY
540LESSONS
112LAB
Objectives
DESCRIPTION OF THE FUNDAMENTAL PROPERTIES OF TRANSITION ELEMENTS AND OF THEIR COMPOUNDS, INCLUDING COORDINATION AND ORGANOMETALLIC COMPLEXES. ENABLE STUDENTS TO APPLY THE KNOWLEDGE OF INORGANIC CHEMISTRY TO SOLVE PRACTICAL SYNTHETIC PROBLEMS, ALSO IN THE LAB WORK.
Prerequisites
BASIC KNOWLEDGE OF GENERAL, INORGANIC AND ORGANIC CHEMISTRY.
Contents
WERNER COMPLEXES. COORDINATION NUMBER AND GEOMETRY. VALENCE BOND THEORY. CRYSTAL FIELD THEORY. MOLECULAR ORBITAL THEORY. CLASSICAL LIGANDS, -BASIC AND -ACID LIGANDS. ORGANOMETALLIC COMPOUNDS. EXAMPLES OF HOMOGENEOUS CATALYSTS.

GENERAL PROPERTIES OF THE TRANSITION ELEMENTS. MAIN COMPOUNDS AND COMPLEXES OF ELEMENTS OF THE FIRST ROW.

LABORATORY: SYNTHESIS AND CHARACTERIZATION OF COORDINATION COMPOUNDS.
Teaching Methods
LECTURES (40 H), LABORATORY (12 H)
Verification of learning
ORAL EXAM, INCLUDING A DISCUSSION OF THE LABORATORY REPORTS.
Texts
HUEHEY, KEITER, KEITER; CHIMICA INORGANICA, ED. PICCIN.
COTTON, WILKINSON; CHIMICA INORGANICA, ED. AMBROSIANA.
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