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COMPLEMENTS OF ORGANIC CHEMISTRY

Annunziata SORIENTE COMPLEMENTS OF ORGANIC CHEMISTRY

0512400022
DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI"
EQF6
CHEMISTRY
2024/2025

YEAR OF COURSE 3
YEAR OF DIDACTIC SYSTEM 2016
SPRING SEMESTER
CFUHOURSACTIVITY
432LESSONS
224EXERCISES
ANNUNZIATA SORIENTE T Curriculum
Objectives
COURSE AIMTHE COURSE AIMS TO CONSOLIDATE THE BASIC CONCEPTS OF ORGANIC CHEMISTRY AND EXPAND KNOWLEDGE TO NEW CLASSES OF COMPOUNDS AND NEW SYNTHETIC PROCEDURES
KNOWLEDGE AND UNDERSTANDING THE STUDENT:
- WILL LEARN ABOUT NEW CLASSES OF ORGANIC COMPOUNDS
- WILL UNDERSTAND THE RELATIONSHIPS BETWEEN THE USE OF A COMPOUND CLASS AND SYNTHETIC EFFICIENCY
APPLYING KNOWLEDGE AND UNDERSTANDING THE STUDENT WILL BE ABLE :
- TO EXAMINE THE SCIENTIFIC LITERATURE
- TO DEVELOP A COMPLEX SYNTHETIC PATH
- TO SOLVE REACTIVITY ISSUES

MAKING JUDGMENTS
THE STUDENT WILL BE ABLE :
- TO EVALUATE THE REACTIVITY OF A CHEMICAL COMPOUND
- TO SELECT AN EFFICIENT SYNTHETIC ROUTE

COMMUNICATION SKILLS
THE STUDENT WILL BE ABLE:
- TO COMMUNICATE IN A FOREIGN LANGUAGE
- TO REPRESENT AND COMMUNICATE RESULTS OF SCIENTIFIC RESEARCH OR ELABORATE OWN CONSIDERATIONS AND COMMENTS

LEARNING SKILL
THE STUDENT WILL BE ABLE :
-TO USE TRADITIONAL BIBLIOGRAPHIC TOOLS AND IT RESOURCES;
- TO CARRY OUT RESEARCH ACTIVITIES;
- TO PROCEED WITH THE CONTINUOUS UPDATING OF YOUR KNOWLEDGE, USING THE
SCIENTIFIC LITERATURE

Prerequisites
THE SUBJECTS TREATED IN THE TEACHING REQUIRED THE BASIC KNOWLEDGE OF ORGANIC CHEMISTRY. IT IS NOT FORMAL PROPHETICITY BUT IS ESSENTIAL FOR THE STUDENT WHO WOULD LIKE TO FOLLOW THE COURSE HE HAD PASSED THE ORGANIC CHEMISTRY I AND II.
Contents
AFTER AN INTRODUCTION ON BASIC ORGANIC CHEMISTRY AND THE REACTIVITY PRINCIPLES, THE 56 HOUR COURSE (6 CFU) CONCERNES THE FOLLOWING TOPICS:
CHEMISTRY OF SULFUR. THE SULFUR ELEMENT AND ITS ORGANIC DERIVATIVES /2H). STABILIZED SULFUR-ANIONS.(2H) SULPHONES AND YLIDES OF SULFUR. SULFUR-CATIONS STABILIZED.(4H) TIO-CARBONYL COMPOUNDS.(4H) SULFOXIDE. OXIDATION REACTIONS WITH SULFUR.(4H)
THE CHEMISTRY OF NITROGEN. AZODERIVATIVES. NITRONES, NITRILOXIDES AND RELATED COMPOUNDS.(4H)
THE CHEMISTRY OF ETHROCYCLIC COMPOUNDS: SATURATED AND AROMATIC ETHEROCICLES CONTAINING MORE THAN ONE HETEROATOMS.(2H) SUMMARY, REACTIVITY AND APPLICATIONS.(4H)
CARBENS AND NITRENES SYNTHESIS AND REACTION OF CARBENS AND NITRENES.(4H)
REARRANGEMENTS: GENERAL CHARACTERISTICS AND CLASSIFICATION. (2H)NUCLEOPHILIC REARRANGEMENTS: MECHANISM, NATURE OF MIGRATION, MIGRATION ATTITUDE AND MEMORY EFFECT.(4H) ELECTROPHILIC REARRANGEMENTS AND RADICALIC (2H) REARRANGEMENTS. LOSSEN AND NEBER REARRANGEMENTS. DIENE-PHENOL REARRANGEMENT. BENZYLIC REARRANGEMENT, FRIES, PAYNE, AND FAVORSKII REARRANGEMENTS.(6H)
RADICAL REACTIONS: SELECTIVITY IN RADICAL CHAIN CHALLENGES(4H). RADICAL CHAIN CONTROL. INTRAMOLECOLAR RADICAL REACTIONS. (4H)HYDROSSILATION TO ALIPHATIC AND AROMATIC CARBON. ALCOOSSILATION AND ACILOSSILATION. (4H)
Teaching Methods
TEACHING PROVIDES LESSONS IN THE CLASSROOM FOR THE PERIOD OF 56 HOURS (6 CFUS), WITH THE PROJECTION AUXILIARY.
Verification of learning
ACHIEVEMENT OF THE OBJECTIVES OF TEACHING IS CERTIFIED BY EXAMINATION OF ORAL EXAMINATION WITH TRENTY ASSESSMENT.
THE ORAL TEST AT A QUESTION WITH QUESTIONS AND DISCUSSION ON THE THEORETICAL AND METHODOLOGICAL CONTENTS INDICATED IN THE PROGRAM OF LEARNING AND IS FINALIZED TO ASSESS THE LEVEL OF KNOWLEDGE AND CAPABILITY OF READING BY THE STUDENT AND TO CHECK THE EXPOSURE CAPACITY BY APPLICABLE TO THE APPROPRIATE TERMINOLOGY .
Texts
F. A. CAREY AND R. J. SUNDBERG, ADVANCED ORGANIC CHEMISTRY, PLENUM PRESS; NEW YORK AND LONDON (III ED.)
J. MARCH, ADVANCED ORGANIC CHEMISTRY, J. WILEY & SONS; NEW YORK (IV ED.)
CLAYDEN, GREEVES, WARREN, WOTHERS, ORGANIC CHEMISTRY, OXFORD UNIVERSITY PRESS; OXFORD AND NEW YORK.
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