ADVANCED PHYSICAL CHEMISTRY

Guglielmo MONACO ADVANCED PHYSICAL CHEMISTRY

0522300009
DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI"
EQF7
CHEMISTRY
2016/2017



OBBLIGATORIO
YEAR OF COURSE 1
YEAR OF DIDACTIC SYSTEM 2016
PRIMO SEMESTRE
CFUHOURSACTIVITY
756LESSONS
224EXERCISES
336LAB
Objectives
OBJECTIVES: I) ACHIEVING KNOWLEDGE AND UNDERSTANDING OF THE LAWS OF THE MICROSCOPIC MATTER; II) ABILITY TO ANALYSE AND EVALUATE SPECTRAL AND OTHER MOLECULAR DATA; III) ABILITY TO COMMUNICATE IN TECHNICAL LANGUAGE; IV) DEVELOPING LEARNING SKILLS NECESSARY FOR PROFESSIONAL LIFE.
Prerequisites
CLASSICAL PHYSICS; DIFFERENTIAL EQUATIONS AND LINEAR ALGEBRA
Contents
LIGHT POLARIZATION AND INTERFERENCE, WAVE PROPERTIES OF PARTICLES. PHOTONS AND QUANTUM STATES. PROBABILITY AMPLITUDES AND SUPERPOSITION PRINCIPLE; FERMIONS AND BOSONS; SCHROEDINGER EQUATIONS. MEASUREMENTS IN QUANTUM MECHANICS. ANGULAR MOMENTUM AND STERN-GERLACH EXPERIMENT. MATRIX REPRESENTATION; EIGENVALUES AND EIGENVECTORS, THE TWO STATE MODEL, EFFECTIVE HAMILTONIAN. VARIATIONAL THEOREM AND PERTURBATION THEORY. IDENTICAL PARTICLE AND ATOMIC STRUCTURE; THE HELIUM ATOM, MULTIELECTRON ATOMS; ATOMIC TERMS. THE BORN-OPPHENEIMER THEOREM, THE THEORY OF CHEMICAL BOND: THE MO AND VB METHODS. HARTREE-FOCK AND DENSITY FUNCTIONAL THEORY METHODS. TIME-DEPENDENT PERTURBATION THEORY; TRANSITION PROBABILITIES; ROTATIONAL, VIBRATIONAL AND ELECTRONIC SPECTROSCOPIES. NON-LINEAR OPTICAL PROPERTIES, TWO PHOTON ABSORPTION AND EMISSION, FREQUENCY CONVERSION. INTERMOLECULAR FORCES.
LABORATORY EXPERIENCES: VIBROROTATIONAL SPECTRUM OF HCL; ROTATIONAL SPECTRUM OF A SYMMETRIC TOP; HUECKEL METHOD; SPECTROSCOPIC DETERMINATION OF A BOND ENERGY: VIBRONIC SPECTRUM OF MOLECULAR IODINE; NUMERICAL APPLICATION OF THE VARIATIONAL METHOD FOR DETERMINING EIGENVALUES AND EIGENFUNCTIONS OF A ONE-DIMENSIONAL ANHARMONIC POTENTIAL; APPLICATIONS OF STATISTICAL TESTS FOR SELECTION OF LINEAR MODELS
Teaching Methods
FRONTAL LECTURES, EXERCISING, LABORATORY EXPERIENCES
Verification of learning
FRONTAL LECTURES, EXERCISING, LABORATORY EXPERIENCES.
Texts
FRENCH, TAYLOR, AN INTRODUCTION TO QUANTUM PHYSICS, MIT PRESS 1985;
FEYNMANN R. LEZIONI DI FISICA, VOL 3;
LEVINE I.N. QUANTUM CHEMISTRY;
HOLLAS, MODERN SPECTROSCOPY, JOHN WILEY & SONS
PARSON MODERN OPTICAL SPECTROSCOPY; SPINGER VERLAG BERLIN 2007
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