Guglielmo MONACO | PHYSICAL CHEMISTRY II

cod. 0512400004

PHYSICAL CHEMISTRY II

	0512400004
	DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI"
	EQF6
	CHEMISTRY
	2022/2023

PERCORSO SHARED STUDY PATHWAY

	OBBLIGATORIO
	YEAR OF COURSE 3
	YEAR OF DIDACTIC SYSTEM 2016
	AUTUMN SEMESTER

TEACHING UNITS

SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
CHIM/02	4	32	LESSONS	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
CHIM/02	1	12	LAB	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
CHIM/02	1	12	EXERCISES	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS

PROFESSORS

	CONSIGLIA TEDESCO T Curriculum
	ALESSANDRO LANDI Curriculum
	GUGLIELMO MONACO Curriculum

	Objectives
	KNOWLEDGE AND UNDERSTANDING: THE TEACHING COURSE WILL PROVIDE A RATIONAL VISION OF THE CHEMICAL-PHYSICAL PHENOMENA OF MULTI-COMPONENT SYSTEMS. STUDENTS WILL ACHIEVE A GENERAL KNOWLEDGE OF PHYSICAL LAWS AND UNDERSTAND AS A CHEMICAL SYSTEM REACHES THE THERMODYNAMIC EQUILIBRIUM. ABILITY TO APPLY KNOWLEDGE AND UNDERSTANDING: STUDENTS WILL BE ABLE TO DETERMINE THE DIRECTION OF PROCESSES, THE COMPOSITION OF REAGENT SYSTEMS AND THEIR KINETIC EVOLUTION. COMMUNICATION SKILLS: STUDENTS WILL BE ABLE TO COMMUNICATE THE CHEMICAL CONCEPTS CLEARLY AND RIGOROUSLY. AUTONOMY OF JUDGMENT: STUDENTS ARE GUIDED TO LEARN CRITICALLY AND RESPONSIBLY AND TO ENRICH THEIR OWN ABILITIES OF JUDGMENT THROUGH THE STUDY OF THE EDUCATIONAL MATERIAL INDICATED BY THE TEACHER.

KNOWLEDGE AND UNDERSTANDING: THE TEACHING COURSE WILL PROVIDE A RATIONAL VISION OF THE CHEMICAL-PHYSICAL PHENOMENA OF MULTI-COMPONENT SYSTEMS. STUDENTS WILL ACHIEVE A GENERAL KNOWLEDGE OF PHYSICAL LAWS AND UNDERSTAND AS A CHEMICAL SYSTEM
REACHES THE THERMODYNAMIC EQUILIBRIUM.
ABILITY TO APPLY KNOWLEDGE AND UNDERSTANDING: STUDENTS WILL BE ABLE TO DETERMINE THE DIRECTION OF PROCESSES, THE COMPOSITION OF REAGENT SYSTEMS AND THEIR KINETIC EVOLUTION.
COMMUNICATION SKILLS: STUDENTS WILL BE ABLE TO COMMUNICATE THE CHEMICAL CONCEPTS CLEARLY AND RIGOROUSLY.
AUTONOMY OF JUDGMENT: STUDENTS ARE GUIDED TO LEARN CRITICALLY AND RESPONSIBLY AND TO ENRICH THEIR OWN ABILITIES OF JUDGMENT THROUGH THE STUDY OF THE EDUCATIONAL MATERIAL INDICATED BY THE TEACHER.

	Prerequisites
	Fundamental knowledge of chemistry, matematics and physics

	Contents
	CHEMICAL THERMODYNAMICS CALORIMETRY. LEGGE DI HESS. PHASE TRANSITIONS. PHASE RULE. PHASE DIAGRAMS. PARTIAL MOLAR QUANTITIES. THE CHEMICAL POTENTIAL. PHASE EQUILIBRIA IN MULTI-COMPONENT SYSTEMS. HOMOGENEOUS AND HETEROGENEOUS SYSTEMS. IDEAL AND NON-IDEAL SOLUTIONS. COLLIGATIVE PROPERTIES. THE PHASE DIAGRAMS OF BINARY SYSTEMS. DIAGRAMS OF VAPOR PRESSURE. TEMPERATURE-COMPOSITION DIAGRAMS. LIQUID-LIQUID PHASE DIAGRAMS. LIQUID-SOLID PHASE DIAGRAMS. THE ACTIVITIES. SOLVENT ACTIVITY. THE ACTIVITY OF THE SOLUTE. THERMODYNAMICS OF CHEMICAL PROCESSES AND CHEMICAL EQUILIBRIUM. THE SPONTANEOUS CHEMICAL REACTIONS. INFLUENCE OF PRESSURE ON CHEMICAL EQUILIBRIUM. THE INFLUENCE OF TEMPERATURE ON THE CHEMICAL EQUILIBRIUM. CHEMICAL KINETICS THE RATE OF REACTION. ORDER OF REACTION AND MOLECULARITY. ELEMENTARY REACTIONS. CATALISI OMOGENEA. INFLUENCE OF TEMPERATURE ON REACTION CONSTANT. HOMOGENEOUS AND HETEROGENEOUS CATALYSIS. CATALYSTS AND THEIR ROLE.

Contents

CHEMICAL THERMODYNAMICS
CALORIMETRY. LEGGE DI HESS. PHASE TRANSITIONS. PHASE RULE. PHASE DIAGRAMS.
PARTIAL MOLAR QUANTITIES. THE CHEMICAL POTENTIAL. PHASE EQUILIBRIA IN MULTI-COMPONENT SYSTEMS. HOMOGENEOUS AND HETEROGENEOUS SYSTEMS. IDEAL AND NON-IDEAL SOLUTIONS.
COLLIGATIVE PROPERTIES. THE PHASE DIAGRAMS OF BINARY SYSTEMS. DIAGRAMS OF VAPOR PRESSURE. TEMPERATURE-COMPOSITION DIAGRAMS. LIQUID-LIQUID PHASE DIAGRAMS. LIQUID-SOLID PHASE DIAGRAMS. THE ACTIVITIES. SOLVENT ACTIVITY. THE ACTIVITY OF THE SOLUTE.
THERMODYNAMICS OF CHEMICAL PROCESSES AND CHEMICAL EQUILIBRIUM.
THE SPONTANEOUS CHEMICAL REACTIONS. INFLUENCE OF PRESSURE ON CHEMICAL EQUILIBRIUM. THE INFLUENCE OF TEMPERATURE ON THE CHEMICAL EQUILIBRIUM.

CHEMICAL KINETICS
THE RATE OF REACTION. ORDER OF REACTION AND MOLECULARITY.
ELEMENTARY REACTIONS. CATALISI OMOGENEA. INFLUENCE OF TEMPERATURE ON REACTION CONSTANT.
HOMOGENEOUS AND HETEROGENEOUS CATALYSIS. CATALYSTS AND THEIR ROLE.

	Teaching Methods
	THE TEACHING COURSE INCLUDES 6 CREDITS DIVIDED INTO 4 CREDITS (32 HOURS) OF LECTURES IN THE CLASSROOM, 1 CREDIT (12 HOURS) OF LABORATORY ACTIVITIES, 1 CREDIT (12 HOURS) OF NUMERICAL EXERCISES.

	Verification of learning
	THE EXAM CONSISTS OF WRITTEN EXERCISES FOLLOWED BY A ORAL DISCUSSION. THREE PROBLEMS SHOULD BE SOLVED IN TWO HOURS TIME. THE EVALUATION WILL TAKE INTO ACCOUNT THE ABILITY TO DEFINE THE CHEMICAL PROBLEM UNDER STUDY BY USING THE RIGHT EQUATIONS, THE ABILITY TO ELABORATE THE DATA BY PERFORMING THE CALCULATIONS CORRECTLY WITH THE RIGHT UNITS OF MEASURE. THE ORAL DISCUSSION WILL TEST THE ABILITY TO EXPLAIN AND DISCUSS THE CONTENTS OF THE TEACHING COURSE. THE EVALUATION IS IN THIRTIETHS.

Verification of learning

THE EXAM CONSISTS OF WRITTEN EXERCISES FOLLOWED BY A ORAL DISCUSSION.
THREE PROBLEMS SHOULD BE SOLVED IN TWO HOURS TIME. THE EVALUATION WILL TAKE INTO ACCOUNT THE ABILITY TO DEFINE THE CHEMICAL PROBLEM UNDER STUDY BY USING THE RIGHT EQUATIONS, THE ABILITY TO ELABORATE THE DATA BY PERFORMING THE CALCULATIONS CORRECTLY WITH THE RIGHT UNITS OF MEASURE.
THE ORAL DISCUSSION WILL TEST THE ABILITY TO EXPLAIN AND DISCUSS THE CONTENTS OF THE TEACHING COURSE.
THE EVALUATION IS IN THIRTIETHS.

	Texts
	1) A. IMMIRZI CHIMICA FISICA. TERMODINAMICA, CUES, 2003. 2) I. N. LEVINE PHYSICAL CHEMISTRY', MCGRAW-HILL, 2009. 3) P. W. ATKINS, J. DE PAULA CHIMICA FISICA ZANICHELLI, 5° ED. ITALIANA BASATA SULLA 9° INGLESE. 4) K. G. DENBIGH, I PRINCIPI DELL'EQUILIBRIO CHIMICO CASA EDITRICE AMBROSIANA, 1977.

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Guglielmo MONACO | PHYSICAL CHEMISTRY II