ALESSANDRO LANDI | PHYSICAL CHEMISTRY II
ALESSANDRO LANDI PHYSICAL CHEMISTRY II
cod. 0512400004
PHYSICAL CHEMISTRY II
0512400004 | |
DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI" | |
EQF6 | |
CHEMISTRY | |
2024/2025 |
OBBLIGATORIO | |
YEAR OF COURSE 3 | |
YEAR OF DIDACTIC SYSTEM 2016 | |
AUTUMN SEMESTER |
SSD | CFU | HOURS | ACTIVITY | |
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CHIM/02 | 4 | 32 | LESSONS | |
CHIM/02 | 1 | 12 | EXERCISES | |
CHIM/02 | 1 | 12 | LAB |
Exam | Date | Session | |
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CHIMICA FISICA II | 24/01/2025 - 10:00 | SESSIONE ORDINARIA | |
CHIMICA FISICA II | 24/01/2025 - 10:00 | SESSIONE DI RECUPERO | |
CHIMICA FISICA II | 21/02/2025 - 10:00 | SESSIONE ORDINARIA | |
CHIMICA FISICA II | 21/02/2025 - 10:00 | SESSIONE DI RECUPERO |
Objectives | |
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THE COURSE AIMS TO PROVIDE A RATIONAL VISION OF THE CHEMICAL-PHYSICAL PHENOMENA IN MULTI-COMPONENT SYSTEMS BY DISCUSSING THE THERMODYNAMIC AND KINETIC ASPECTS. KNOWLEDGE AND UNDERSTANDING: THE STUDENT - WILL KNOW THE FUNDAMENTALS OF THE THERMODYNAMIC LAWS OF MULTICOMPONENT AND MULTIPHASE SYSTEMS - WILL KNOW THE LAWS THAT DESCRIBE THE EVOLUTION OF CHEMICAL REACTIONS OVER TIME - WILL UNDERSTAND THE ROLE OF TEMPERATURE AND PRESSURE ON THE CHEMICAL EQUILIBRIUM AND HOW TO PROMOTE CHEMICAL REACTIONS FROM A THERMODYNAMIC AND KINETIC POINT OF VIEW. ABILITY TO APPLY KNOWLEDGE AND UNDERSTANDING: THE STUDENT WILL BE ABLE TO: - SOLVE THERMODYNAMIC AND KINETIC PROBLEMS APPLIED TO CHEMICAL REACTIONS - PROCESS THE DATA OBTAINED FROM A SCIENTIFIC EXPERIMENT AND REPORT THEM IN A SCIENTIFIC REPORT WITH THE RELATED EXPERIMENTAL ERRORS CRITICAL ASSESSMENT: THE STUDENT WILL BE ABLE TO: - EVALUATE THE RELIABILITY OF THE RESULTS OBTAINED IN SOLVING THEORETICAL PROBLEMS - EVALUATE THE RELIABILITY OF THE EXPERIMENTAL RESULTS IN THE CONTEXT OF THE SCIENTIFIC LITERATURE COMMUNICATION SKILLS: THE STUDENT WILL BE ABLE TO: - REPRESENT AND COMMUNICATE, THROUGH TEXTS OR VIRTUAL TOOLS, THE RESULTS OF RESEARCH OR OWN ELABORATIONS. LEARNING ABILITY: THE STUDENT WILL BE ABLE TO: - USE TRADITIONAL BIBLIOGRAPHIC TOOLS AND IT ANALYSIS AND ARCHIVING RESOURCES; - PROCEED WITH THE CONTINUOUS UPDATING OF HIS/HER KNOWLEDGE, USING THE TECHNICAL AND SCIENTIFIC LITERATURE |
Prerequisites | |
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FUNDAMENTAL KNOWLEDGE OF CHEMISTRY, MATHEMATICS AND PHYSICS |
Contents | |
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CHEMICAL THERMODYNAMICS CALORIMETRY. LEGGE DI HESS. PHASE TRANSITIONS. PHASE RULE. PHASE DIAGRAMS. PARTIAL MOLAR QUANTITIES. THE CHEMICAL POTENTIAL. PHASE EQUILIBRIA IN MULTI-COMPONENT SYSTEMS. HOMOGENEOUS AND HETEROGENEOUS SYSTEMS. IDEAL AND NON-IDEAL SOLUTIONS. COLLIGATIVE PROPERTIES. THE PHASE DIAGRAMS OF BINARY SYSTEMS. DIAGRAMS OF VAPOR PRESSURE. TEMPERATURE-COMPOSITION DIAGRAMS. LIQUID-LIQUID PHASE DIAGRAMS. LIQUID-SOLID PHASE DIAGRAMS. THE ACTIVITIES. SOLVENT ACTIVITY. THE ACTIVITY OF THE SOLUTE. THERMODYNAMICS OF CHEMICAL PROCESSES AND CHEMICAL EQUILIBRIUM. THE SPONTANEOUS CHEMICAL REACTIONS. INFLUENCE OF PRESSURE ON CHEMICAL EQUILIBRIUM. THE INFLUENCE OF TEMPERATURE ON THE CHEMICAL EQUILIBRIUM. CHEMICAL KINETICS THE RATE OF REACTION. ORDER OF REACTION AND MOLECULARITY. ELEMENTARY REACTIONS. CATALISI OMOGENEA. INFLUENCE OF TEMPERATURE ON REACTION CONSTANT. HOMOGENEOUS AND HETEROGENEOUS CATALYSIS. CATALYSTS AND THEIR ROLE. PRACTICAL SESSIONS IN THE LABORATORY COMPLETE THE COURSE. |
Teaching Methods | |
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THE TEACHING COURSE INCLUDES 6 CREDITS DIVIDED INTO 4 CREDITS (32 HOURS) OF LECTURES IN THE CLASSROOM, 1 CREDIT (12 HOURS) OF LABORATORY ACTIVITIES, 1 CREDIT (12 HOURS) OF NUMERICAL EXERCISES. |
Verification of learning | |
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THE EXAM CONSISTS OF WRITTEN EXERCISES FOLLOWED BY A ORAL DISCUSSION. THREE PROBLEMS SHOULD BE SOLVED IN TWO HOURS TIME. THE EVALUATION WILL TAKE INTO ACCOUNT THE ABILITY TO DEFINE THE CHEMICAL PROBLEM UNDER STUDY BY USING THE RIGHT EQUATIONS, THE ABILITY TO ELABORATE THE DATA BY PERFORMING THE CALCULATIONS WITH THE CORRECT UNITS OF MEASURE. THE ORAL DISCUSSION WILL TEST THE ABILITY TO EXPLAIN AND DISCUSS THE CONTENTS OF THE TEACHING COURSE. THE EVALUATION IS IN THIRTIETHS. STUDENTS HAVE THE POSSIBILITY TO PARTICIPATE TO 3 INTERMEDIATE TESTS, THAT WILL EXEMPT THEM FROM THE FINAL WRITTEN EXAMINATION. |
Texts | |
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1) T. ENGEL, P. REID, CHIMICA FISICA - TERMODINAMICA, TERMODINAMICA STATISTICA E CINETICA, PICCIN EDITORE 2023 2) I. N. LEVINE PHYSICAL CHEMISTRY', MCGRAW-HILL, 2009. 3) S. CAPASSO, L. AMBROSONE, G. MONACO, S. SALVESTRINI, A. VERGARA, ELEMENTI DI CHIMICA FISICA, 2021, ISBN 9798769453793 4) P. W. ATKINS, J. DE PAULA CHIMICA FISICA ZANICHELLI, 5° ED. ITALIANA BASATA SULLA 9° INGLESE. 5) A. IMMIRZI CHIMICA FISICA. TERMODINAMICA, CUES, 2003. |
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