Consiglia TEDESCO | PHYSICAL CHEMISTRY II
Consiglia TEDESCO PHYSICAL CHEMISTRY II
cod. 0512400004
PHYSICAL CHEMISTRY II
0512400004 | |
DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI" | |
EQF6 | |
CHEMISTRY | |
2023/2024 |
OBBLIGATORIO | |
YEAR OF COURSE 3 | |
YEAR OF DIDACTIC SYSTEM 2016 | |
AUTUMN SEMESTER |
SSD | CFU | HOURS | ACTIVITY | |
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CHIM/02 | 4 | 32 | LESSONS | |
CHIM/02 | 1 | 12 | EXERCISES | |
CHIM/02 | 1 | 12 | LAB |
Objectives | |
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KNOWLEDGE AND UNDERSTANDING: THE TEACHING COURSE WILL PROVIDE A RATIONAL VISION OF THE CHEMICAL-PHYSICAL PHENOMENA OF MULTI-COMPONENT SYSTEMS. STUDENTS WILL ACHIEVE A GENERAL KNOWLEDGE OF PHYSICAL LAWS AND UNDERSTAND AS A CHEMICAL SYSTEM REACHES THE THERMODYNAMIC EQUILIBRIUM. ABILITY TO APPLY KNOWLEDGE AND UNDERSTANDING: STUDENTS WILL BE ABLE TO DETERMINE THE DIRECTION OF PROCESSES, THE COMPOSITION OF REAGENT SYSTEMS AND THEIR KINETIC EVOLUTION. COMMUNICATION SKILLS: STUDENTS WILL BE ABLE TO COMMUNICATE THE CHEMICAL CONCEPTS CLEARLY AND RIGOROUSLY. AUTONOMY OF JUDGMENT: STUDENTS ARE GUIDED TO LEARN CRITICALLY AND RESPONSIBLY AND TO ENRICH THEIR OWN ABILITIES OF JUDGMENT THROUGH THE STUDY OF THE EDUCATIONAL MATERIAL INDICATED BY THE TEACHER. |
Prerequisites | |
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FUNDAMENTAL KNOWLEDGE OF CHEMISTRY, MATHEMATICS AND PHYSICS |
Contents | |
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CHEMICAL THERMODYNAMICS CALORIMETRY. LEGGE DI HESS. PHASE TRANSITIONS. PHASE RULE. PHASE DIAGRAMS. PARTIAL MOLAR QUANTITIES. THE CHEMICAL POTENTIAL. PHASE EQUILIBRIA IN MULTI-COMPONENT SYSTEMS. HOMOGENEOUS AND HETEROGENEOUS SYSTEMS. IDEAL AND NON-IDEAL SOLUTIONS. COLLIGATIVE PROPERTIES. THE PHASE DIAGRAMS OF BINARY SYSTEMS. DIAGRAMS OF VAPOR PRESSURE. TEMPERATURE-COMPOSITION DIAGRAMS. LIQUID-LIQUID PHASE DIAGRAMS. LIQUID-SOLID PHASE DIAGRAMS. THE ACTIVITIES. SOLVENT ACTIVITY. THE ACTIVITY OF THE SOLUTE. THERMODYNAMICS OF CHEMICAL PROCESSES AND CHEMICAL EQUILIBRIUM. THE SPONTANEOUS CHEMICAL REACTIONS. INFLUENCE OF PRESSURE ON CHEMICAL EQUILIBRIUM. THE INFLUENCE OF TEMPERATURE ON THE CHEMICAL EQUILIBRIUM. CHEMICAL KINETICS THE RATE OF REACTION. ORDER OF REACTION AND MOLECULARITY. ELEMENTARY REACTIONS. CATALISI OMOGENEA. INFLUENCE OF TEMPERATURE ON REACTION CONSTANT. HOMOGENEOUS AND HETEROGENEOUS CATALYSIS. CATALYSTS AND THEIR ROLE. PRACTICAL SESSION IN THE LABORATORY COMPLETE THE COURSE. |
Teaching Methods | |
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THE TEACHING COURSE INCLUDES 6 CREDITS DIVIDED INTO 4 CREDITS (32 HOURS) OF LECTURES IN THE CLASSROOM, 1 CREDIT (12 HOURS) OF LABORATORY ACTIVITIES, 1 CREDIT (12 HOURS) OF NUMERICAL EXERCISES. |
Verification of learning | |
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THE EXAM CONSISTS OF WRITTEN EXERCISES FOLLOWED BY A ORAL DISCUSSION. THREE PROBLEMS SHOULD BE SOLVED IN TWO HOURS TIME. THE EVALUATION WILL TAKE INTO ACCOUNT THE ABILITY TO DEFINE THE CHEMICAL PROBLEM UNDER STUDY BY USING THE RIGHT EQUATIONS, THE ABILITY TO ELABORATE THE DATA BY PERFORMING THE CALCULATIONS WITH THE CORRECT UNITS OF MEASURE. THE ORAL DISCUSSION WILL TEST THE ABILITY TO EXPLAIN AND DISCUSS THE CONTENTS OF THE TEACHING COURSE. THE EVALUATION IS IN THIRTIETHS. STUDENTS HAVE THE POSSIBILITY TO PARTICIPATE TO 3 INTERMEDIATE TESTS, THAT WILL EXEMPT THEM FROM THE FINAL WRITTEN EXAMINATION. |
Texts | |
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1) A. IMMIRZI CHIMICA FISICA. TERMODINAMICA, CUES, 2003. 2) I. N. LEVINE PHYSICAL CHEMISTRY', MCGRAW-HILL, 2009. 3) P. W. ATKINS, J. DE PAULA CHIMICA FISICA ZANICHELLI, 5° ED. ITALIANA BASATA SULLA 9° INGLESE. 4) K. G. DENBIGH, I PRINCIPI DELL'EQUILIBRIO CHIMICO CASA EDITRICE AMBROSIANA, 1977. |
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