Maria Ricciardi | INSTRUMENTAL ANALYTICAL CHEMISTRY

cod. 0512400001

INSTRUMENTAL ANALYTICAL CHEMISTRY

	0512400001
	DEPARTMENT OF CHEMISTRY AND BIOLOGY "ADOLFO ZAMBELLI"
	EQF6
	CHEMISTRY
	2024/2025

PERCORSO SHARED STUDY PATHWAY Cohort 2022/2023

	OBBLIGATORIO
	YEAR OF COURSE 3
	YEAR OF DIDACTIC SYSTEM 2016
	FULL ACADEMIC YEAR

TEACHING UNITS

SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
CHIM/01	3	24	LESSONS	SUPPLEMENTARY COMPULSORY SUBJECTS
CHIM/01	1	12	EXERCISES	SUPPLEMENTARY COMPULSORY SUBJECTS
CHIM/01	2	24	LAB	SUPPLEMENTARY COMPULSORY SUBJECTS

PROFESSORS

	TONINO CARUSO T Curriculum
	MARIA RICCIARDI Curriculum

	Objectives
	GENERAL OBJECTIVE. THE COURSE HAS THE MAIN OBJECTIVE OF TRAINING THE CANDIDATE IN KNOWING HOW TO CARRY OUT CHEMICAL ANALYZES OF DIFFERENT MATRICES KNOWLEDGE AND UNDERSTANDING. KNOWLEDGE OF THE MAIN ANALYSIS TECHNIQUES AND UNDERSTANDING OF THE CHEMICAL-PHYSICAL FACTORS RESPONSIBLE FOR PROCESS VARIATIONS ABILITY TO APPLY KNOWLEDGE AND UNDERSTANDING. THE STUDENT WILL BE ABLE TO IDENTIFY AND OPTIMIZE ANALYSIS METHODS FOR EACH CLASS OF ANALYTE AUTONOMY OF JUDGEMENT. CORRECTLY CONDUCT AN ANALYSIS PROCESS. KNOWING HOW TO APPLY THE PRINCIPLES OF THE CHOSEN INSTRUMENTAL TECHNIQUE, EVALUATING BASED ON THE EVIDENCE WHICH PARAMETERS TO OPTIMIZE. COMMUNICATION SKILLS. KNOWING HOW TO WORK IN A GROUP IN A LABORATORY CONTEXT. KNOW HOW TO EXPLAIN THE PROBLEMS CONNECTED TO CHEMICAL ANALYSIS PROCESSES WITH PROPER LANGUAGE. LEARNING ABILITY. THE STUDENT WILL BE ABLE TO APPLY THE KNOWLEDGE ACQUIRED TO REAL CONTEXTS SIMILAR TO THOSE PRESENTED DURING THE COURSE, AND TO DELVE DEEPER INTO THE TOPICS COVERED IN SITUATIONS DIFFERENT FROM THOSE PROPOSED.

GENERAL OBJECTIVE.
THE COURSE HAS THE MAIN OBJECTIVE OF TRAINING THE CANDIDATE IN KNOWING HOW TO CARRY OUT CHEMICAL ANALYZES OF DIFFERENT MATRICES
KNOWLEDGE AND UNDERSTANDING.
KNOWLEDGE OF THE MAIN ANALYSIS TECHNIQUES AND UNDERSTANDING OF THE CHEMICAL-PHYSICAL FACTORS RESPONSIBLE FOR PROCESS VARIATIONS
ABILITY TO APPLY KNOWLEDGE AND UNDERSTANDING.
THE STUDENT WILL BE ABLE TO IDENTIFY AND OPTIMIZE ANALYSIS METHODS FOR EACH CLASS OF ANALYTE
AUTONOMY OF JUDGEMENT.
CORRECTLY CONDUCT AN ANALYSIS PROCESS.
KNOWING HOW TO APPLY THE PRINCIPLES OF THE CHOSEN INSTRUMENTAL TECHNIQUE, EVALUATING BASED ON THE EVIDENCE WHICH PARAMETERS TO OPTIMIZE.
COMMUNICATION SKILLS.
KNOWING HOW TO WORK IN A GROUP IN A LABORATORY CONTEXT. KNOW HOW TO EXPLAIN THE PROBLEMS CONNECTED TO CHEMICAL ANALYSIS PROCESSES WITH PROPER LANGUAGE.
LEARNING ABILITY.
THE STUDENT WILL BE ABLE TO APPLY THE KNOWLEDGE ACQUIRED TO REAL CONTEXTS SIMILAR TO THOSE PRESENTED DURING THE COURSE, AND TO DELVE DEEPER INTO THE TOPICS COVERED IN SITUATIONS DIFFERENT FROM THOSE PROPOSED.

	Prerequisites
	BASIC KNOWLEDGE OF MATHEMATICS, PHYSICS, CHEMISTRY GENERAL INORGANIC CHEMISTRY, ANALYTICAL CHEMISTRY AND ORGANIC CHEMISTRY

	Contents
	1.STOICHIOMETRY. ACIDS AND BASES. CHEMICAL EQUILIBRIA. (12 H) 2.QUALITATIVE AND QUANTITATIVE ANALYSIS. ACCURACY, PRECISION, SENSITIVITY, SPECIFICITY AND REPRODUCIBILITY IN THE MEASUREMENT. STRAIGHT LINE CALIBRATION METHOD OF STANDARD ADDITIONS AND THE INTERNAL STANDARD. DETECTION LIMITS. (12 H) 3.OPTICAL METHODS. RADIATION INTERACTION. LAMBERT-BEER'LAW: VALIDITY AND DEVIATIONS. ATOMIC AND MOLECULAR ABSORPTION. INSTRUMENTATION. BANDWIDTH AND RESOLVING POWER. PHOTOMETRIC ERROR. DETERMINATION OF METALS AND METABOLITES (CHOLESTEROL, TRIGLYCERIDES, SUGARS ...). (12 H) 4.ELECTROCHEMICAL METHODS. ELECTRODES: BEHAVIOUR OF NERNST'S LAW. SENSITIVITY. PRECISION. ION-SELECTIVE MEMBRANE ELECTRODES. EFFICIENCY OF PH-METER. DETERMINATION OF ACIDITY, ANIONS, METALS, UREA, DISSOLVED GASES, GLUCOSE (12 H) 5.CHROMATOGRAPHIC METHODS. SOLVENT EXTRACTION, SPE ED SPME. EQUATION VAN DEEMTER. PERFORMANCE OF A COLUMN: EFFICIENCY AND RESOLUTION. SELECTIVITY. SHAPE OF THE CHROMATOGRAPHIC BAND. GLC AND GSC. CAPILLARY COLUMNS. DETECTORS: SENSITIVITY, STABILITY, SPECIFICITY. FID, MS, TCD, NPD, ECD. PURGE&TRAP AND HEAD SPACE. ISOTHERMS AND TEMPERATURE PROGRAMMING. DETERMINATION OF HYDROCARBONS, ALCOHOLS, PESTICIDES, VOLATILE ORGANIC COMPOUNDS (VOC). HPLC. COLUMNS: NORMAL OR REVERSE PHASE. ISOCRATIC ELUTION AND GRADIENT. IONIC CHROMATOGRAPHY. CONDUCTIMETRY. DETERMINATION OF VITAMINS, PESTICIDES, DRUGS AND ANIONS. (12 H)

Contents

1.STOICHIOMETRY. ACIDS AND BASES. CHEMICAL EQUILIBRIA. (12 H)
2.QUALITATIVE AND QUANTITATIVE ANALYSIS. ACCURACY, PRECISION, SENSITIVITY, SPECIFICITY AND REPRODUCIBILITY IN THE MEASUREMENT. STRAIGHT LINE CALIBRATION METHOD OF STANDARD ADDITIONS AND THE INTERNAL STANDARD. DETECTION LIMITS. (12 H)
3.OPTICAL METHODS. RADIATION INTERACTION. LAMBERT-BEER'LAW: VALIDITY AND DEVIATIONS. ATOMIC AND MOLECULAR ABSORPTION. INSTRUMENTATION. BANDWIDTH AND RESOLVING POWER. PHOTOMETRIC ERROR. DETERMINATION OF METALS AND METABOLITES (CHOLESTEROL, TRIGLYCERIDES, SUGARS ...). (12 H)
4.ELECTROCHEMICAL METHODS. ELECTRODES: BEHAVIOUR OF NERNST'S LAW. SENSITIVITY. PRECISION. ION-SELECTIVE MEMBRANE ELECTRODES. EFFICIENCY OF PH-METER. DETERMINATION OF ACIDITY, ANIONS, METALS, UREA, DISSOLVED GASES, GLUCOSE (12 H)
5.CHROMATOGRAPHIC METHODS. SOLVENT EXTRACTION, SPE ED SPME. EQUATION VAN DEEMTER. PERFORMANCE OF A COLUMN: EFFICIENCY AND RESOLUTION. SELECTIVITY. SHAPE OF THE CHROMATOGRAPHIC BAND. GLC AND GSC. CAPILLARY COLUMNS. DETECTORS: SENSITIVITY, STABILITY, SPECIFICITY. FID, MS, TCD, NPD, ECD. PURGE&TRAP AND HEAD SPACE. ISOTHERMS AND TEMPERATURE PROGRAMMING. DETERMINATION OF HYDROCARBONS, ALCOHOLS, PESTICIDES, VOLATILE ORGANIC COMPOUNDS (VOC). HPLC. COLUMNS: NORMAL OR REVERSE PHASE. ISOCRATIC ELUTION AND GRADIENT. IONIC CHROMATOGRAPHY. CONDUCTIMETRY. DETERMINATION OF VITAMINS, PESTICIDES, DRUGS AND ANIONS. (12 H)

	Teaching Methods
	LECTURES IN THE CLASSROOM WITH PROJECTION OF TEACHING MATERIALS IN ELECTRONIC FORM, AVAILABLE ON THE WEBSITE HTTP://DOCENTI.UNISA.IT/004719/RISORSE. LABORATORY TESTS AND EXERCISES IN CLASS ON THE ACTIVITIES CARRIED OUT IN THE LABORATORY.

	Verification of learning
	LABORATORY TESTS WITH ASSESSMENT. EXPERIMENTAL DATA. WRITTEN TEST.

	Texts
	1.A. PELOSO, PROBLEMI DI CHIMICA GENERALE, CORTINA ED., PADOVA, 2006. 2.SKOOG D. A, HOLLER, F. J., CROUCH, S. R., CHIMICA ANALITICA STRUMENTALE, 2A ED. EDISES 2009 3.D. HARRIS, CHIMICA ANALITICA QUANTITATIVA, ZANICHELLI, BOLOGNA, 2004. 4.CHIMICA ANALITICA CLINICA, C. D'OVIDIO, U. DE GRAZIA, P. LANUTI, M. LOCATELLI, M. MARCHISIO, G.M. MERONE, E. ROSATO, F. SAVINI, A. TARTAGLIA, ED. EDISES 2021 5.SPETTROMETRIA DI MASSA, DI J. H. GROSS. ED. EDISES 2016, PER LA PARTE RELATIVA 6.LEZIONI DI ELETTROCHIMICA, BRUNO MAZZA, EDISES ED. 2019, PER PARTE RELATIVA 7. SKOOG D. A, HOLLER, F. J., CROUCH, S. R., CHIMICA ANALITICA STRUMENTALE, 2A ED. EDISES 2009.

Texts

1.A. PELOSO, PROBLEMI DI CHIMICA GENERALE, CORTINA ED., PADOVA, 2006.
2.SKOOG D. A, HOLLER, F. J., CROUCH, S. R., CHIMICA ANALITICA STRUMENTALE, 2A ED. EDISES 2009
3.D. HARRIS, CHIMICA ANALITICA QUANTITATIVA, ZANICHELLI, BOLOGNA, 2004.
4.CHIMICA ANALITICA CLINICA, C. D'OVIDIO, U. DE GRAZIA, P. LANUTI, M. LOCATELLI, M. MARCHISIO, G.M. MERONE, E. ROSATO, F. SAVINI, A. TARTAGLIA, ED. EDISES 2021
5.SPETTROMETRIA DI MASSA, DI J. H. GROSS. ED. EDISES 2016, PER LA PARTE RELATIVA
6.LEZIONI DI ELETTROCHIMICA, BRUNO MAZZA, EDISES ED. 2019, PER PARTE RELATIVA
7. SKOOG D. A, HOLLER, F. J., CROUCH, S. R., CHIMICA ANALITICA STRUMENTALE, 2A ED. EDISES 2009.

	More Information
	RECOMMENDED ATTENDANCE OF THE CLASS COURSE, THE LABORATORY TESTS ARE OBLIGATORY. WHO IS NOT PRESENT OVER 25% OF THE LABORATORY TEST IS NOT ADMITTED TO THE FINAL EXAM.

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Maria Ricciardi | INSTRUMENTAL ANALYTICAL CHEMISTRY