Mina MAZZEO | INORGANIC CHEMISTRY I

cod. 0512400006

INORGANIC CHEMISTRY I

	0512400006
	DIPARTIMENTO DI CHIMICA E BIOLOGIA "ADOLFO ZAMBELLI"

	CHEMISTRY
	2015/2016

PERCORSO COMUNE

	OBBLIGATORIO
	YEAR OF COURSE 2
	YEAR OF DIDACTIC SYSTEM 2010
	PRIMO SEMESTRE

TEACHING UNITS

	SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
1	CHIMICA INORGANICA I MODULO A
	CHIM/03	5	40	LESSONS	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
	CHIM/03	1	12	LAB	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
2	CHIMICA INORGANICA I MODULO B
	CHIM/03	3	24	LESSONS	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
	CHIM/03	1	12	EXERCISES	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
	CHIM/03	2	24	LAB	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS

PROFESSORS

	CHIARA COSTABILE2 T Curriculum
	MINA MAZZEO1 Curriculum

	Objectives
	KNOWLEDGE AND UNDERSTANDING: THE AIM IS TO INTRODUCE THE STUDENT TO THE SYSTEMATIC UNDERSTANDING OF THE STRUCTURE AND PROPERTIES OF THE MAIN GROUPS ELEMENTS AND RELATED COMPOUNDS WITH REFERENCE TO THE PERIODIC PROPERTIES AND THE LOCATION OF THE ELEMENT IN THE PERIODIC TABLE. SOME REPRESENTATIVE EXAMPLES OF SYNTHETIC PROCEDURE ON INDUSTRIAL SCALE OF WIDELY USED INORGANIC COMPOUNDS WILL BE GIVEN AS WELL AS THEIR APPLICATIONS IN EVERY-DAY LIFE APPLYING KNOWLEDGE AND UNDERSTANDING: AT THE END OF THIS CLASS THE STUDENT WILL BE ABLE TO AFFORD THE BASICAL INORGANIC SYNTHESIS AND WILL HAVE THE BASICAL KNOWLEDGE FOR THE COMPREHENSION FOR MORE ADVANCED INORGANIC CHEMISTRY CLASSES. MAKING JUDGEMENTS: STUDENTS ARE STIMULATED TO LEARN IN A DISCRIMINATING WAY EVERYTHING IS PRESENTED DURING THE LESSON THROUGH GROUP EXERCISES, QUESTIONS AND DISCUSSIONS ON EACH ARGUMENT. COMMUNICATION SKILLS: STUDENTS ARE STIMULATED TO IMPROVE THEIR WRITTEN COMUNICATION SKILLS, THROUGH LABORATORY REPORTS AT THE AND OF EACH EXERCISES, AND THEIR ORAL COMUNICATION SKILLS IN PROSPECT OF THE FINAL ORAL EXAM LEARNING SKILLS: THIS CLASS IS BASED ON THE KNOWLEDGE OF THE GENERAL CHEMISTRY AND AIM TO GIVE KNOWLEDGE ON INORGANIC CHEMISTRY OF MAIN CHEMICAL COMPOUNDS. THE COMPREHENSION OF ITS TOPICS IS FACILITATED BY CLASS AND LABORATORY EXECISES.

KNOWLEDGE AND UNDERSTANDING:
THE AIM IS TO INTRODUCE THE STUDENT TO THE SYSTEMATIC UNDERSTANDING OF THE STRUCTURE AND PROPERTIES OF THE MAIN GROUPS ELEMENTS AND RELATED COMPOUNDS WITH REFERENCE TO THE PERIODIC PROPERTIES AND THE LOCATION OF THE ELEMENT IN THE PERIODIC TABLE. SOME REPRESENTATIVE EXAMPLES OF SYNTHETIC PROCEDURE ON INDUSTRIAL SCALE OF WIDELY USED INORGANIC COMPOUNDS WILL BE GIVEN AS WELL AS THEIR APPLICATIONS IN EVERY-DAY LIFE
APPLYING KNOWLEDGE AND UNDERSTANDING:
AT THE END OF THIS CLASS THE STUDENT WILL BE ABLE TO AFFORD THE BASICAL INORGANIC SYNTHESIS AND WILL HAVE THE BASICAL KNOWLEDGE FOR THE COMPREHENSION FOR MORE ADVANCED INORGANIC CHEMISTRY CLASSES.

MAKING JUDGEMENTS:
STUDENTS ARE STIMULATED TO LEARN IN A DISCRIMINATING WAY EVERYTHING IS PRESENTED DURING THE LESSON THROUGH GROUP EXERCISES, QUESTIONS AND DISCUSSIONS ON EACH ARGUMENT.

COMMUNICATION SKILLS:
STUDENTS ARE STIMULATED TO IMPROVE THEIR WRITTEN COMUNICATION SKILLS, THROUGH LABORATORY REPORTS AT THE AND OF EACH EXERCISES, AND THEIR ORAL COMUNICATION SKILLS IN PROSPECT OF THE FINAL ORAL EXAM

LEARNING SKILLS:
THIS CLASS IS BASED ON THE KNOWLEDGE OF THE GENERAL CHEMISTRY AND AIM TO GIVE KNOWLEDGE ON INORGANIC CHEMISTRY OF MAIN CHEMICAL COMPOUNDS. THE COMPREHENSION OF ITS TOPICS IS FACILITATED BY CLASS AND LABORATORY EXECISES.

	Prerequisites
	BASIC CHEMISTRY. IN ORDER TO ATTEND LABORATORY CLASSES, TO OVERTAKE GENERAL AND INORGANIC CHEMISTRY EXAM IS MADATORY.

	Contents
	THE STRUCTURE OF THE ATOM AND THE PERIODIC TABLE OF THE ELEMENTS. IONIC SOLIDS. MAIN IONIC LATTICES. DEFECTS IN IONIC SOLIDS. COVALENT BOND. VALENCE BOND THEORY. MOLECULAR ORBITAL THEORY. METALS. INTRODUCTION TO SYMMETRY. THE STRUCTURE OF MOLECULES. ACID-BASE CHEMISTRY. CHEMICAL FORCES. GENERAL PROPERTIES OF THE ELEMENTS. GENERAL METHODS FOR THE ISOLATION OF PURE ELEMENTS. HYDROGEN. THE ALKALI METALS. INDUSTRY FOR THE PRODUCTION OF CHLORINE AND ALKALINE COMPOUNDS: LEBLANC, WELDON AND DEACON PROCESSES. SOLVAY PROCESS. THE ALKALINE EARTHS. DOW PROCESS. BORON, BORIDES AND BORANES. ALUMINIUM AND ALUMINIUM OXIDES. TRIVALENT HALIDES OF BORON AND ALUMINIUM. CARBON. IONIC, COVALENT AND INTERSTITIAL CARBIDES. CO AND CO2. CARBONIC ACID. CYANIDRIC ACID AND CYANIDES. SILICON AND RELATED MOLECULAR COMPOUNDS. SILICATES. SILICONS. NITROGEN AND RELATED HYDRIDES AND OXIDES. BIOLOGICAL CYCLE OF NITROGEN. HABER PROCESS. NITRIC AND NITROUS ACIDS. NITRIDES. PHOSPHOROUS AND RELATED HALIDES, OXIDES AND OXIACIDS. POLYPHOSPHATES. OXYGEN AND OXIDES. OZONE. SULFUR AND RELATED OXIDES AND HALIDES. SULFURIC AND SULFUROUS ACIDS. HALOGENS AND HALIDES. HALOGENIDRIC ACIDS. OXIDES AND OXOACIDS OF HALOGENS. INTERHALOGENIC COMPOUNDS. NOBLE GASES. ZINC, CADMIUM AND MERCURY. LABORATORY: 1)PREPARATION OF IRON OXIDES. 2)ALKALI METAL REACTIVITY. 3)SYNTHESIS OF NA2CO3. 4)ALKALINE EARTH METAL OXALATES PREPARATION AND ANALYSIS. 5)SYNTHESIS OF AL(ACAC)3. 6)SYNTHESIS OF HNO3 7) VISIT OF THE MINERALOGICAL MUSEUM OF NAPOLI

Contents

THE STRUCTURE OF THE ATOM AND THE PERIODIC TABLE OF THE ELEMENTS. IONIC SOLIDS. MAIN IONIC LATTICES. DEFECTS IN IONIC SOLIDS. COVALENT BOND. VALENCE BOND THEORY. MOLECULAR ORBITAL THEORY. METALS. INTRODUCTION TO SYMMETRY. THE STRUCTURE OF MOLECULES. ACID-BASE CHEMISTRY. CHEMICAL FORCES. GENERAL PROPERTIES OF THE ELEMENTS. GENERAL METHODS FOR THE ISOLATION OF PURE ELEMENTS. HYDROGEN. THE ALKALI METALS. INDUSTRY FOR THE PRODUCTION OF CHLORINE AND ALKALINE COMPOUNDS: LEBLANC, WELDON AND DEACON PROCESSES. SOLVAY PROCESS. THE ALKALINE EARTHS. DOW PROCESS. BORON, BORIDES AND BORANES. ALUMINIUM AND ALUMINIUM OXIDES. TRIVALENT HALIDES OF BORON AND ALUMINIUM. CARBON. IONIC, COVALENT AND INTERSTITIAL CARBIDES. CO AND CO2. CARBONIC ACID. CYANIDRIC ACID AND CYANIDES. SILICON AND RELATED MOLECULAR COMPOUNDS. SILICATES. SILICONS. NITROGEN AND RELATED HYDRIDES AND OXIDES. BIOLOGICAL CYCLE OF NITROGEN. HABER PROCESS. NITRIC AND NITROUS ACIDS. NITRIDES. PHOSPHOROUS AND RELATED HALIDES, OXIDES AND OXIACIDS. POLYPHOSPHATES. OXYGEN AND OXIDES. OZONE. SULFUR AND RELATED OXIDES AND HALIDES. SULFURIC AND SULFUROUS ACIDS. HALOGENS AND HALIDES. HALOGENIDRIC ACIDS. OXIDES AND OXOACIDS OF HALOGENS. INTERHALOGENIC COMPOUNDS. NOBLE GASES. ZINC, CADMIUM AND MERCURY.
LABORATORY:
1)PREPARATION OF IRON OXIDES.
2)ALKALI METAL REACTIVITY.
3)SYNTHESIS OF NA2CO3.
4)ALKALINE EARTH METAL OXALATES PREPARATION AND ANALYSIS.
5)SYNTHESIS OF AL(ACAC)3.
6)SYNTHESIS OF HNO3
7) VISIT OF THE MINERALOGICAL MUSEUM OF NAPOLI

	Teaching Methods
	LESSONS. EXERCISES. LABORATORY.

	Verification of learning
	PRACTICE EXERCISES IN CLASS. LABORATORY REPORT AND ASSESSMENT QUESTIONNAIRES. ORAL EXAM.

	Texts
	J. D. LEE “CONCISE INORGANIC CHEMISTRY “ ED. WILEY-BLACKWELL. J.E. HUHEEY “INORGANIC CHEMISTRY” ED. HARPER COLLINS. F.A. COTTON, J. WILKINSON “INORGANIC CHEMISTRY” V ED- WILEY-INTERSCIENCE. P. W. ATKINS, T. OVERTON, J. ROURKE, M. WELLER, F. ARMSTRONG “INORGANIC CHEMISTRY” ED. ZANICHELLI

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Mina MAZZEO | INORGANIC CHEMISTRY I